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Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network

DOI: 10.1039/C8CC03838D DOI Help

Authors: Michael Zaworotko (University of Limerick) , Shiqiang Wang (University of Limerick) , Qing-yuan Yang (University of Limerick) , Soumya Mukherjee (University of Limerick) , Daniel O'nolan (University of Limerick) , Ewa Patyk-kazmierczak (University of Limerick) , Kai Jie Chen (University of Limerick) , Mohana Shivanna (University of Limerick) , Claire Murray (Diamond Light Source) , Chiu Tang (Diamond Light Source)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications

State: Published (Approved)
Published: May 2018
Diamond Proposal Number(s): 16167

Abstract: A nonporous square lattice (sql) coordination network [Co(bipy)2(NCS)2]n (sql-1-Co-NCS) exhibits recyclable switching induced by CO2. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.

Subject Areas: Chemistry, Energy


Instruments: I11-High Resolution Powder Diffraction