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Hybrid organic-inorganic rotaxanes, including a hetero-hybrid [3]rotaxane featuring two distinct heterometallic rings and a molecular shuttle

DOI: 10.1002/anie.201805439 DOI Help

Authors: Grigore A. Timco (The University of Manchester) , Antonio Fernandez (The University of Manchester) , Andreas K. Kostopoulos (The University of Manchester) , Jodie F. Charlton (The University of Manchester) , Selena J. Lockyer (The University of Manchester) , Thomas R. Hailes (The University of Manchester) , Ralph W. Adams (The University of Manchester) , Eric J. L. Mcinnes (The University of Manchester) , Floriana Tuna (The University of Manchester) , IƱigo J. Vitorica-yrezabal (The University of Manchester) , George F. S. Whitehead (The University of Manchester) , Richard E. P. Winpenny (The University of Manchester)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Angewandte Chemie International Edition , VOL 57 , PAGES 10919 - 10922

State: Published (Approved)
Published: August 2018
Diamond Proposal Number(s): 17379

Abstract: [2] and [3] hybrid rotaxanes are reported based on {Ti7M} rings (M is a trivalent metal such as FeIII or GaIII). NMR studies show that [2]rotaxanes can act as molecular shuttles, while EPR studies of [3]rotaxanes show weak interactions between the paramagnetic components of the supramolecular assemblies.

Subject Areas: Chemistry, Energy, Materials


Instruments: I19-Small Molecule Single Crystal Diffraction