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Abstract: Three-dimensional (3D) topologicalWeyl semimetals (TWSs) represent a state of quantum matter with unusual electronic structures that resemble both a ‘3D graphene’ and a topological insulator. Their electronic structure displays pairs of Weyl points (through which the electronic bands disperse linearly along all three momentum directions) connected by topological surface states, forming a unique arc-like Fermi surface (FS). Each Weyl point is chiral and contains half the degrees of freedom of a Dirac point, and can be viewed as a magnetic monopole in momentum space. By performing angle-resolved photoemission spectroscopy on the non-centrosymmetric compound TaAs, here we report its complete band structure, including the unique Fermi-arc FS and linear bulk band dispersion across the Weyl points, in agreement with the theoretical calculations1, 2. This discovery not only confirms TaAs as a 3DTWS, but also provides an ideal platform for realizing exotic physical phenomena (for example, negative magnetoresistance, chiral magnetic effects and the quantum anomalous Hall effect) which may also lead to novel future applications.

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Abstract: The layered compound Ni2P2S6 was electrochemically characterized for application as anode material in sodium-ion batteries (SIBs). A high reversible capacity of 621 mAh g 1 at 1 A g 1 was achieved after 190 cycles. The investigation of the complex reaction mechanism of the conversion reaction was performed applying complementary techniques including X-ray powder diffraction, pair distribution function analyses, X-ray absorption spectroscopy, 19F/23Na/31P MAS NMR, TEM and nano-EDX. The results highlight that Na uptake for up to 5 Na/formula unit (f.u.) led to reduction of Ni2+ to metallic Ni nanoparticles and concomitant formation of an intermediate compound Na4P2S6. Increasing the Na content to 12 Na/f.u. generates nanocrystalline Na2S, which is accompanied by loss of the long-range order of the pristine sample. In the completely discharged state elemental Ni and Na2S are present, but in contrast to literature reports, no evidence for the formation of NaxP phases was found. During the charge process, Ni3S2 is formed upon the release of ~11.7 Na/f.u. A very high specific capacity of 621 mAh g 1 at 1.0 A g 1 is obtained after 190 cycles, and Coulombic efficiencies reach nearly 100% after the 3rd cycle.

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Abstract: Materials used as electrodes in energy storage devices have been extensively studied with solid-state NMR spectroscopy. Due to the almost ubiquitous presence of transition metals, these systems are also often magnetic. While it is well known that the presence of anisotropic bulk magnetic susceptibility (ABMS) leads to broadening of resonances under MAS, we show that for mono-disperse and non-spherical particle morphologies, the ABMS can also lead to considerable shifts, which vary substantially as a function of particle shape. This, on one hand, complicates the interpretation of the NMR spectrum and the ability to compare the measured shift of different samples of the same system. On the other hand the ABMS shift provides a mechanism with which to derive the particle shape from the NMR spectrum. In this work, we present a methodology to model the ABMS shift, and relate it to the shape of the studied particles. The approach is tested on the $^7$Li NMR spectra of single crystals and powders of LiFePO$_4$. The results show that the ABMS shift can be a major contribution to the total NMR shift in systems with large magnetic anisotropies and small hyperfine shifts, $^7$Li shifts for typical LiFePO$_4$ morphologies varying by as much as 100 ppm. The results are generalised to demonstrate that the approach can be used as a means with which to probe the aspect ratio of particles. The work has implications for the analysis of NMR spectra of all materials with anisotropic magnetic susceptibilities, including diamagnetic materials such as graphite.

Open Access

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Abstract: A new family of eight dinuclear iridium(III) complexes has been prepared, featuring 4,6-diarylpyrimidines Ly as bis-N^C-coordinating bridging ligands. The metal ions are also coordinated by a terminal N^C^Ncyclometallating ligand LX based on 1,3-di(2-pyridyl)benzene, and by a monodentate chloride or cyanide. The general formula of the compounds is {IrLXZ}2Ly (Z = Cl or CN). The family comprises examples with three different LX ligands and five different diarylpyrimidines Ly, of which four are diphenylpyrimidines and one is a dithienylpyrimidine. The requisite proligands have been synthesised via standard cross-coupling methodology. The synthesis of the complexes involves a two-step procedure, in which LXH is reacted with IrCl3·3H2O to form dinuclear complexes of the form [IrLXCl(μ-Cl)]2, followed by treatment with the diarylpyrimidine LyH2. Crucially, each complex is formed as a single compound only: the strong trans influence of the metallated rings dictates the relative disposition of the ligands, whilst the use of symmetrically substituted tridentate ligands eliminates the possibility of Λ and Δ enantiomers that are obtained when bis-bidentate units are linked through bridging ligands. The crystal structure of one member of the family has been obtained using a synchrotron X-ray source. All of the complexes are very brightly luminescent, with emission maxima in solution varying over the range 517–572 nm, according to the identity of the ligands. The highest-energy emitter is the cyanide derivative whilst the lowest is the complex with the dithienylpyrimidine. The trends in both the absorption and emission energies as a function of ligand substituent have been rationalised accurately with the aid of TD-DFT calculations. The lowest-excited singlet and triplet levels correlate with the trend in the HOMO–LUMO gap. All the complexes have quantum yields that are close to unity and phosphorescence lifetimes – of the order of 500 ns – that are unusually short for complexes of such brightness. These impressive properties stem from an unusually high rate of radiative decay, possibly due to spin–orbit coupling pathways being facilitated by the second metal ion, and to low non-radiative decay rates that may be related to the rigidity of the dinuclear scaffold.

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Abstract: Higher whole grain cereal intakes are associated with substantially lower risks of type 2 diabetes, coronary heart disease, and hypertension. These reduced risks have been established in large prospective studies that now include millions of person-years of follow-up. We analyze the results of 11 major prospective studies to provide recommendations about whole grain consumption. The following review establishes the amount of whole grains that should ideally be consumed based on prospective evidence; defines the nature of whole grains; identifies that the whole grain evidence is robust and not due to confounding; and provides a detailed assessment of several potential mechanisms for the effect of whole grains on health. We draw the following conclusions. Firstly, to maintain health, 40 grams or more of whole grains should be consumed daily. This is about a bowl of whole grain breakfast cereal daily, but 80% of the population does not achieve this. Secondly, aleurone in bran is a critical grain component generally overlooked in favor of indigestible fiber. Live aleurone cells constitute 50% of millers' bran. They store minerals, protein, and the antioxidant ferulic acid, and are clearly more than just indigestible fiber. Finally, we suggest potential roles for magnesium, zinc, and ferulic acid in the development of chronic disease. If the results of prospective studies were applied to the life-style practices of modern societies there exists the potential for enormous personal health and public financial benefits.